June 2018

Special Focus: Process Optimization

Remove carbonyls from gaseous hydrocarbon streams for ethylene plant service

Within the hydrocarbon processing industry (HPI), particularly the petrochemical sector, there remains an irritating series of reactions associated with acid gas removal (AGR) using dilute caustic soda—namely, aldol condensation reactions and their respective products.

Gondolfe, J., Kurukchi, S., Janus Technology Solutions LLC

Within the hydrocarbon processing industry (HPI), particularly the petrochemical sector, there remains an irritating series of reactions associated with acid gas removal (AGR) using dilute caustic soda—namely, aldol condensation reactions and their respective products. These reaction products cause fouling effects within the AGR itself and, perhaps more importantly, subsequent treatment of the spent solution from the AGR. It is well understood that the speciation of these highly reactive compounds can be classified as carbonyls. Reactions of carbonyls are catalyzed in the presence of free caustic in an aqueous solution to produce aldol condensation products. A method to pretreat these carbo

Log in to view this article.

Not Yet A Subscriber? Here are Your Options.

1) Start a FREE TRIAL SUBSCRIPTION and gain access to all articles in the current issue of Hydrocarbon Processing magazine.

2) SUBSCRIBE to Hydrocarbon Processing magazine in print or digital format and gain ACCESS to the current issue as well as to 3 articles from the HP archives per month. $409 for an annual subscription*.

3) Start a FULL ACCESS PLAN SUBSCRIPTION and regain ACCESS to this article, the current issue, all past issues in the HP Archive, the HP Process Handbooks, HP Market Data, and more. $1,995 for an annual subscription.  For information about group rates or multi-year terms, contact email Peter Ramsay or call +44 20 3409 2240*.

*Access will be granted the next business day.

Related Articles

From the Archive

Comments

Comments

{{ error }}
{{ comment.comment.Name }} • {{ comment.timeAgo }}
{{ comment.comment.Text }}